This paper shows how biographical registries can be represented as Linked Data, enriched by data linking to related data sources, and used in Digital Humanities. As a use case, a database of 11 987 historical U.S. Congress Legislators in 1789–2018 was transformed into a knowledge graph. The data was published as a Linked Data service, including a SPARQL endpoint, on top of which tools for biographical and prosopographical research are implemented. A faceted browser named U.S. Congress Prosopographer with visualization tools for knowledge discovery is presented to provide new insights in political history.