Tellurium(II)-Centered Dications from the Pseudohalide “Te(OTf)2”
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Tellurium(II)-Centered Dications from the Pseudohalide “Te(OTf)2”
telluriumii centered dications from the pseudohalide teotf2.pdf
(University of Jyväskylä - JYX)
Te for two: Supported by pyridine- or carbene-based ligands, tellurium-centered dications are prepared in high yield and include a dicationic tellurium analogue of the recently synthesized “carbodicarbene”. The key to accessing these compounds is the isolation of a base-stabilized form of TeOTf2 (see structure), a new highly electrophilic reagent for tellurium chemistry.
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Language |
English |
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Series | Angewandte Chemie, International Edition, 24 |
Subjects | |
ISSN |
1433-7851 |